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Convert TIN to Raster using: 3D Analyst > Convert TIN to Raster. Set the cell size to a round number, e.g. 5.
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Convert Raster to Point Shape file using: 3D Analyst > Convert Raster to Features
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Set Output geometry type to “Point”
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[alternative: use ArcToolbox > Conversion Tools > Raster to Point]
 
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Convert Shape to xyz file using: ArcToolbox > Spatial Statistics Tools > Utilities > Export Feature Attribute to ASCII
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Check GRID_CODE
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Delimiter = comma
 
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The grid needs to be regular, with no holes, and a perfectly rectangular outline. If it is not, preprocess using Datgel Survey Tool > Grid File Pre-processing Tool